Radical addition-coupling polymerization (RACP) of various benzyl-type biradical toward periodic polymers

Periodic polymers with different repeating units were synthesized by radical addition-coupling polymerization (RACP) of bifunctional monomers with benzyl bromide/α-methyl benzyl bromide groups and 2-methyl-2-nitrosopropane in the presence of Cu(0)/ligand.148