کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5179339 1502513 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chiral fluorescence polyethers based on BINOL for enantioselective recognition of phenylalanine anion
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Chiral fluorescence polyethers based on BINOL for enantioselective recognition of phenylalanine anion
چکیده انگلیسی


• BINOL-based fluorescence sensors with two chiral moieties were reported.
• Enantioselective recognition was conducted in aqueous solution of THF/H2O.
• Configurations of both BINOL and ECH affect the selectivity.
• The value of enantiomeric fluorescence difference ratio (ef) reached to 6.29.

Series of polyethers with different configurations were synthesized from chiral BINOL and optical epichlorohydrin. The optical behavior of the obtained polyethers is evaluated with specific optical rotation, UV–vis spectroscopy, circular dichroism (CD) and fluorescence spectroscopy. Thermogravimetric analysis (TGA) reveals the polyethers a good thermal stability. The fluorescence responses of the chiral polyethers on chiral phenylalanine anion were investigated. The sensors (S,S)-4 and (R,R)-4 showed high enantioselective fluorescent sensing ability to phenylalanine anion. The value of enantiomeric fluorescence difference ratio (ef) reached to 6.29.

Series of polyethers with different configurations were synthesized from chiral BINOL and optical epichlorohydrin. The sensors (S,S)-4 and (R,R)-4 showed high enantioselective fluorescent sensing ability to phenylalanine anion. The value of enantiomeric fluorescence difference ratio (ef) reached to 6.29.Figure optionsDownload high-quality image (169 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 93, 14 June 2016, Pages 9–13