کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5179589 | 1502518 | 2016 | 10 صفحه PDF | دانلود رایگان |
- Poly(benzoxazole-co-imide)s films with tunable physical properties are prepared.
- High temperature multiple-shape memory behaviors of poly(benzoxazole-co-imide)s are demonstrated.
- Potential mechanism of multiple-shape memory effects is suggested.
High temperature triggered multiple-shape memory poly(benzoxazole-co-imide)s with adjustable properties were prepared via facile random copolymerization 3,3â²,4,4â²-biphenyltetracarbolylic dianhydride (BPDA) with two different diamine of 4,4â²-oxydianiline (ODA) and 5-amino-2-(4-aminobenzene) benzoxazole (BOA). The effect of polybenzoxazole on the molecular packing, physical properties and shape memory behaviors of poly(benzoxazole-co-imide)s was investigated systematically. The incorporation of polybenzoxazole into polyimides endows better mechanical properties, higher chain packing, broad glass transition temperature and excellent tunable dual-shape memory behaviors with shape fixity above 98% and shape recovery up to 98%. Besides, multiple-shape memory effects with high switching temperature are first achieved in poly(benzoxazole-co-imide)s, and the multiple-shape memory could be adjusted by choosing the two different switching temperatures. Lastly, the potential mechanism of multiple-shape memory behaviors of poly(benzoxazole-co-imide)s are suggested.
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Journal: Polymer - Volume 88, 6 April 2016, Pages 19-28