کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5179598 1502518 2016 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A comparative parameter study: Controlling fiber diameter and diameter distribution in centrifugal spinning of photocurable monomers
ترجمه فارسی عنوان
مطالعه ی پارامتر مقایسه ای: کنترل قطر فیبر و توزیع قطر در چرخش گریز از مونومرهای قابل احتراق
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


• Fibers with tunable diameters were produced via UV-reactive centrifugal spinning.
• Factors controlling diameter in reactive and solution spinning were compared.
• Average fiber diameter and diameter distribution can be tailored independently.
• Crosslinked thiol-ene fibers with average diameter as small as 1.5 μm were made.

In this study, the key factors for controlling the average fiber diameter and diameter distribution of fibers made via simultaneous centrifugal spinning and UV initiated polymerization are elucidated. Through systematic investigation, it was found that the average fiber diameter has a strong dependence on monomer delivery rate through the orifice, which can be intuitively linked to both the orifice diameter and monomer mixture viscosity. On the other hand, the breadth of the fiber diameter distribution can be controlled by the spin speed of the rotating spinneret. Carefully tuning these process parameters allows near independent control of average fiber diameter and its distribution, which could provide access to a widely tailorable range of fibers appropriate for different applications. Finally, under optimized process conditions, crosslinked fibers with average diameters of approximately 1.5 μm can be produced, which are one to two orders of magnitude smaller than photocured fibers fabricated in previous reports and comparable with the smallest melt blown nonwoven fibers produced commercially. Coupled with the advantages of cross-linked fibers made by in-situ photopolymerization, the capability to produce small fibers with tailored diameter distributions by centrifugal spinning could further establish this technology as a competitive alternative to existing approaches.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 88, 6 April 2016, Pages 102–111