کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5180909 | 1380946 | 2014 | 12 صفحه PDF | دانلود رایگان |
The structural evolution of nanoparticles (NPs) dispersion under uniaxial stretching and extension/retraction deformation cycles above Tg was investigated in model silica/polymethylmethacrylate (PMMA) nanocomposites (PNCs) by a combination of Small Angle X-ray Scattering (SAXS) and Transmission Electronic Microscopy (TEM). The different structure displacements and reorganizations can be quantitatively characterized as a function of elongation ratio, silica volume fraction and NP size. At low NP volume fraction, a rotation/orientation of non-connected aggregates is observed along the stretching direction, while the reinforcement is low and might be limited by the large-scale aggregates. At high volume fraction, the stress-strain curves exhibit three regimes. (i) At low stretching ratio, in the linear deformation regime, reinforcement is driven by the primary network filler structure. (ii) Above a few percent of deformation, a yield is observed and can be associated to the network breakdown as revealed by cyclic extension/retraction experiments. (iii) As a result of this yield, at larger deformation, the stress curve appears as shifted upward with respect to the one of pure polymer. A persistence of this vertical shift (constant value up to large deformation) might be related with SAXS measurements to a non-affine deformation of the NPs network due to new structural arrangements, while in a second case, the decrease of stress to the pure polymer value with increasing deformation is related with observation of affine deformation after the yield. Finally, affinity and non-affinity after yielding are discussed for all the systems according to the strength of the NP-NP interaction.
Journal: Polymer - Volume 55, Issue 10, 13 May 2014, Pages 2523-2534