کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5181678 | 1380969 | 2014 | 12 صفحه PDF | دانلود رایگان |
This paper describes the preparations and lithium-ion conductivities of various solid polymer electrolytes for potential use in high-energy density lithium-ion batteries. The ring opening polymerization of epoxides (M1–M6), catalyzed by Zn(II), Cu(II) and Cd(II) complexes in the presence of tetrabutylammonium bromide (TBAB), yielded polyethers (P1–P6) in which phosphates were attached as pendant groups. A reaction condition where Zn(II) catalyst used slightly excess to TBAB increased the polymerization rate remarkably and yielded the polyethers with higher molar masses in a short time. These polymerizations proceeded following a “monomer activated anionic ring opening polymerization” mechanism. These living like polymerizations also progressed according to “formation of polymer chain per initiator” model. The solid-state lithium-ion conductivities of these polymers were examined using lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). The conductivity of one of the solid polymer electrolytes with 40 wt% of LiTFSI was 5.2 × 10−5 S cm−1 at room temperature and 2.9 × 10−4 S cm−1 at 80 °C.
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Journal: Polymer - Volume 55, Issue 1, 14 January 2014, Pages 83–94