کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5182494 1380991 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Aqueous emulsion polymerization of styrene and substituted styrenes using titanocene compounds
ترجمه فارسی عنوان
پلیمریزاسیون آب امولسیون استایرن و استرین های جایگزین با استفاده از ترکیبات تیتانوسن
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی

Aqueous emulsion polymerization of styrene in the presence of half-titanocenes which CpTiCl3, (CpCH2CH2OCH3)TiCl3, and of the titanocene (Ph)2C[(Cp)(Flu)Ti]Cl2 is effected. The polymer features are compared with those of polystyrene obtained in the same reaction conditions, by using Cp2TiCl2 as initiator.Titanocene (Ph)2C[(Cp)(Flu)Ti]Cl2 does not show any activity in styrene polymerization. On the contrary, by using both half-titanocenes CpTiCl3 and (CpCH2CH2OCH3)TiCl3, stereoirregular polystyrene is produced. Aqueous emulsion polymerization of substituted styrenes (3-methyl-styrene, 4-methyl-styrene, 3-chloro-styrene, 4-chloro-styrene) is also performed in the presence of Cp2TiCl2. From all monomers, stereoirregular polymers are obtained. Monomer reactivity results dependent on the substituent on the aromatic ring. Aqueous emulsion styrene - 4-chloro-styrene copolymerizations are performed by using Cp2TiCl2, too. Copolymer composition totally reflects that of comonomers used in the feeding. According to a statistical distribution of comonomers, the product of the reactivity ratios is 1.1.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 54, Issue 6, 8 March 2013, Pages 1583-1587
نویسندگان
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