کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5183157 | 1381010 | 2012 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Melt fracture of HDPEs: Metallocene versus Ziegler-Natta and broad MWD effects
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The melt fracture of high-density polyethylenes (HDPEs) is studied primarily as a function of molecular weight and its distribution for broad molecular weight distribution metallocene and Ziegler-Natta catalyst resins. It is found that sharkskin and other melt fracture phenomena are very different for these two classes of polymers, although their rheological behaviors are nearly the same for many of these. Moreover, the metallocene HDPE shows significant slip at the die wall without exhibiting stick-slip transition. Important correlations are derived between the critical conditions for the onset of melt fracture and molecular characteristics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 53, Issue 19, 31 August 2012, Pages 4195-4201
Journal: Polymer - Volume 53, Issue 19, 31 August 2012, Pages 4195-4201
نویسندگان
Mahmoud Ansari, Yong W. Inn, Ashish M. Sukhadia, Paul J. DesLauriers, Savvas G. Hatzikiriakos,