کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5183365 | 1381016 | 2012 | 11 صفحه PDF | دانلود رایگان |
Novel amphiphilic ethyl cellulose (EC) brush polymers with mono and dual side chains of poly(2-(2-methoxyethoxy)ethyl methacrylate)-co-oligo(ethylene glycol) methacrylate) (P(MEO2MA-co-OEGMA)) and poly(2-(N,N-dimethylamino)ethyl methacrylate) (PDMAEMA) were synthesized by the combination of atom transfer radical polymerization (ATRP) and click chemistry. The molar ratio of P(MEO2MA-co-OEGMA) and PDMAEMA was varied through changing the feed ratio of these polymers and the coupling efficiency of click chemistry is relatively high. The brush polymers can self-assemble into spherical micelles/aggregates. The micelles/aggregates show the tunable temperature-pH responsive properties. The cloud points and the pH-triggered phase transition were influenced by EC chains and the ratio of P(MEO2MA-co-OEGMA) and PDMAEMA side chains. The brush polymers have the great potential applications as biomedical or intelligent materials.
Journal: Polymer - Volume 53, Issue 4, 17 February 2012, Pages 956-966