کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5183880 | 1381031 | 2011 | 14 صفحه PDF | دانلود رایگان |
The microstructure and mechanical properties of melt-spun isotactic polypropylene (iPP) fibers were studied for different take-up velocities and throughputs with a combination of small- and wide-angle X-ray scattering, calorimetry and tensile tests. With the increase of take-up velocity the mesomorphic fraction of the fibers steadily decreases while the crystalline fraction increases. The addition of an alpha-nucleating agent led to an increase of crystallinity and a slight decrease of the orientation factor. By contrast, a beta-nucleator resulted in a complete suppression of the fiber crystallinity. The orientation factor of the mesophase and/or crystalline phase is found to have a one-to-one correlation with the fiber tenacity and deformation at break. At the same time, the absolute values of crystallinity and/or mesomorphicity are fully uncorrelated with these mechanical characteristics. The observed correlations can be used for example to design and control the fiber mechanical properties by tuning the processing conditions such as take-up velocity, throughput and addition of nucleating agents.
Journal: Polymer - Volume 52, Issue 24, 10 November 2011, Pages 5630-5643