کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5184235 1381042 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization
چکیده انگلیسی

Monodisperse magnetic poly(glycidyl methacrylate) microspheres were prepared by dispersion polymerization of glycidyl methacrylate in cyclohexane in the presence of La0.75Sr0.25MnO3 nanoparticles, surface of which was modified with penta(propylene glycol) methacrylate phosphate (PPGMAP). However, only agglomerates were formed by the dispersion polymerization in toluene. Sterical stabilizer was poly(styrene-block-hydrogenated butadiene-block-styrene) and initiators investigated were 2,2′-azobisisobutyronitrile (AIBN) and 4,4′-azobis(4-cyanovaleric acid) (ACVA). Effects of initiators and other reaction conditions on properties of the composite microspheres were evaluated. The phase composition of the magnetic polymer composite microspheres and the size of magnetic cores were determined by X-ray powder diffraction. The characterization was completed by magnetization measurements, atomic absorption spectroscopy, TEM, SEM and ATR FTIR spectroscopy.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 51, Issue 14, 24 June 2010, Pages 3116-3122
نویسندگان
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