کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5184918 | 1381061 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
[NCO]/[OH] and acryl-polyol concentration dependence of the gelation process and the microstructure analysis of polyurethane resin by dynamic light scattering
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The gelation process and the microstructure after the gelation of polyurethane resin consisting of acryl-polyol and polyisocyanate was investigated by dynamic light scattering (DLS) as a function of stoichiometric ratio, [NCO]/[OH], and the concentration of acryl-polyol, Cpolyol. The following conclusions were obtained. First, the sol-gel transition was explained by the so-called site-bond percolation theory. Here polyol groups act as site-occupants, and isocyanate groups act as chemical cross-linkers. Second, the scattering inhomogeneities increased rather gradually around the gelation point, which are the characteristics of the gelation process not from monomeric but from oligomer units. Third, at the gelation point, the characteristic decay time of the fast mode, Ïfast, decreased, and the fraction of the collective diffusion mode, A, increased with [NCO]/[OH], which are due to introduction of cross-linking and/or increase of the rigidity of the network. Finally, the ensemble average scattering intensities, ãIãE, the static inhomogeneities, ãICãE, the time-average dynamic fluctuating component, ãIFãT and the collective diffusion coefficient, D, showed remarkable dependence not only on Cpolyol but also on [NCO]/[OH]. These are due to the competition between the cross-linking and the progress of micro-phase separation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 50, Issue 11, 22 May 2009, Pages 2503-2509
Journal: Polymer - Volume 50, Issue 11, 22 May 2009, Pages 2503-2509
نویسندگان
Takuya Suzuki, Mitsuhiro Shibayama, Kazuhiro Hatano, Masahiko Ishii,