کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5185120 | 1381068 | 2008 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Feature ArticleReversible chain transfer catalyzed polymerization (RTCP): A new class of living radical polymerization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This article introduces the new family of living radical polymerizations with germanium (Ge), tin (Sn), phosphorus (P), and nitrogen (N) catalysts which we recently developed. The polymerizations are based on a new reversible activation mechanism, Reversible chain Transfer (RT) catalysis. Low-polydispersity polymers are obtained in the homopolymerizations and random and block copolymerizations of styrene, methyl methacrylate, and functional methacrylates. The background, performance, and kinetic features of the polymerizations are described. Attractive features of the catalysts include their high reactivity, low toxicity (Ge, P, and N), low cost (P and N), and ease of handling (robustness).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 24, 10 November 2008, Pages 5177-5185
Journal: Polymer - Volume 49, Issue 24, 10 November 2008, Pages 5177-5185
نویسندگان
Atsushi Goto, Yoshinobu Tsujii, Takeshi Fukuda,