کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5185311 1381074 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
چکیده انگلیسی

Several non-metallocene-type titanium(IV) complexes containing phenoxy-phosphine or thiophenoxy-phosphine ligands of type, (2-R1-4-R2-6-PPh2-C6H2X)2TiCl2 (2a: X = O, R1 = R2 = t-Bu; 2b: X = O, R1 = R2 = cumyl; 2c: X = S, R1 = SiMe3, R2 = H) have been synthesized by treating TiCl4 with the corresponding ligands 2-R1-4-R2-6-PPh2-C6H2XH in the presence of n-BuLi. The complexes 2a-c were investigated as the catalysts for ethylene with 1-hexene and/or polar alkenes copolymerizations. The catalytic activity and the comonomer incorporation were highly dependent upon catalyst and reaction conditions employed. Among these complexes, 2a can not only promote ethylene/1-hexene living copolymerization at room temperature, but also can utilize ethylene with methyl 10-undecenoate copolymerization.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 51, Issue 19, 3 September 2010, Pages 4336-4339
نویسندگان
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