کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5185450 | 1381077 | 2010 | 5 صفحه PDF | دانلود رایگان |
The dimensions of linear polymer chains are scaled to their molar mass (M) as R = kMα with α = 1/2 and 3/5 in a theta and an athermal solvent, respectively. In a good solvent, both k and α are a function of the solvent quality and chain length range. A high-temperature laser light-scattering spectrometer was used to measure the average radius of gyration (ãRgã) and hydrodynamic radius (ãRhã) of a set of narrowly distributed linear polystyrene chains in decalin over a wide temperature range. k and α in the scaling experimentally varying with T over a chain length range was analyzed. The results reveal that for ãRgã, α = 0.59 â 0.09exp(âÏ/0.066) and k = 0.60Ï2αâ1, reasonably agreeing with the thermal blob theory. For ãRhã, α = 0.59 â 0.09exp(âÏ/0.106), but k deviates from the relationship of k â Ï2αâ1, reflecting that the hydrodynamic interaction and chain draining are not considered in the thermal blob theory.
Journal: Polymer - Volume 51, Issue 6, 11 March 2010, Pages 1413-1417