کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5185580 1381082 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation and characterization of thiourea encapsulated polyethylene oxide
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Formation and characterization of thiourea encapsulated polyethylene oxide
چکیده انگلیسی
The structure and dynamics of PEO chains encapsulated in thiourea (TU) channels formed in the PEO-TU-inclusion compound (PEO-TU-IC) were studied by XRD, FTIR and solid state NMR spectroscopy. XRD and FTIR observations clearly show PEO-TU-IC adopts a crystal structure different from neat thiourea, and the usual rhombohedral crystal structure of thiourea small molecule ICs. PEO chains in the channel adopt a conformation similar to bulk PEO, as confirmed by solid state NMR spectroscopy. Contact-time array (VCT) NMR profiles shows that PEO chains in the TU channels are considerably more mobile than in bulk PEO. Infrared bands for the PEO shift in the IC, and these were attributed to changes in the secondary forces.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 2, 21 January 2008, Pages 374-377
نویسندگان
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