کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5185728 | 1381086 | 2009 | 7 صفحه PDF | دانلود رایگان |
Polyacrylamide (PAAm) hydrogels possessing a very large extensibility at break have been prepared via micellar crosslinking copolymerization of acrylamide monomer and N,Nâ²-methylenebis(acrylamide) crosslinker in the presence of hydrophobic comonomers. N-butyl-, N-hexyl-, N-octyl-, and N,N-dihexylacrylamides were used as the hydrophobes in the hydrogel preparation. Incorporation of hydrophobes with an alkyl chain length x > 4 results in an increase in the loss factor tan δ of hydrogels due to the formation of temporary junction zones inside the gel network. The number NH of the hydrophobes per hydrophobic block together with the alkyl chain length x of the pendant hydrophobic group were used to tune the loss factor of the hydrogels over two orders of magnitude. Tensile mechanical measurements show that increasing NH or x also increases the degree of toughness of PAAm hydrogels. Keeping constant the hydrophobe level (20 mol%) at an alkyl chain length x = 6, increasing NH from 9 to 30 increased the elongation ratio at break from 125 to 250%. Hydrogels exhibiting a high toughness, i.e., about 300% elongation ratio at break were obtained by modification of PAAm network chains with 10 mol% N-octylacrylamide.
Journal: Polymer - Volume 50, Issue 23, 3 November 2009, Pages 5449-5455