کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5185979 1381092 2007 17 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mechanism of ɛ-caprolactone polymerization and ɛ-caprolactone/trimethylene carbonate copolymerization carried out with Zr(Acac)4
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Mechanism of ɛ-caprolactone polymerization and ɛ-caprolactone/trimethylene carbonate copolymerization carried out with Zr(Acac)4
چکیده انگلیسی

The paper presents the mechanism of the polymerization of ɛ-caprolactone with the use of Zr(Acac)4. At the first stage of the initiation of the polymerization, a reaction consisting of proton transfer from caprolactone to acetylacetonate ligand and then ligand exchange reaction with release of free acetylacetone (HAcac) occur. Complex 1, arisen as a product of this reaction, is the actual initiator of the observed polymerization. During the conducted polymerization the molar mass increase is directly proportional to monomer conversion degree. On the basis of observed phenomenon, the polymerization of cyclic trimethylene carbonate (TMC) applying ɛ-caprolactone as a co-initiator is possible. Complex 1 arose in the initial phase of this reaction as well, being an equally efficient initiator for TMC polymerization. Using Zr(Acac)4 as an initiator for an ɛ-caprolactone/TMC copolymerization resulted in obtaining a series of copolymers with varied, predicted composition and high molar mass values.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 48, Issue 8, 5 April 2007, Pages 2263-2279
نویسندگان
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