کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186120 1381096 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gel formation and primary chain lengths in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Gel formation and primary chain lengths in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion
چکیده انگلیسی

Gelation in 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO)-mediated cross-linking copolymerization of styrene and divinylbenzene (8.2 mol%) in aqueous miniemulsion at 125 °C has been investigated. The rate of gel formation relative to monomer conversion was the same in miniemulsion and the corresponding solution polymerization when the organic phase contained 6 vol% tetradecane (TD; hydrophobe) and 48 vol% toluene. However, at 54 vol% TD and no toluene (the same total monomer concentration), the conversion at the gel point was lower in miniemulsion than in solution, consistent with our previous results describing enhanced apparent pendant reactivity related to the presence of TD in the present system. The primary chain lengths were higher in miniemulsion with 54 vol% TD than in miniemulsion with 6 vol% TD and in solution (6 and 54 vol% TD). It was deduced via application of Flory-Stockmayer gelation theory that this difference in primary chain lengths, although significant with regards to gelation, was insufficient to explain the rapid gel formation in the miniemulsion containing 54 vol% TD, which is speculated to be related to specific effects of the heterogeneity of the miniemulsion system.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 48, Issue 5, 23 February 2007, Pages 1229-1236
نویسندگان
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