کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186159 1381097 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of molecularly imprinted polymer microspheres via reversible addition-fragmentation chain transfer precipitation polymerization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Preparation of molecularly imprinted polymer microspheres via reversible addition-fragmentation chain transfer precipitation polymerization
چکیده انگلیسی

The first combined use of reversible addition-fragmentation chain transfer (RAFT) polymerization and precipitation polymerization in the molecular imprinting field is described. The new polymerization technique, namely RAFT precipitation polymerization (RAFTPP), provides MIP microspheres with obvious molecular imprinting effects towards the template, fast template binding process and an appreciable selectivity over structurally related compounds, while only irregular MIP aggregates were obtained via traditional radical precipitation polymerization (TRPP) under similar reaction conditions. The MIP microspheres prepared via RAFTPP have proven to show improved binding capacity, larger binding constant and apparent maximum number for high-affinity sites, and significantly higher high-affinity binding site density in comparison with the MIP prepared via TRPP.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 50, Issue 13, 19 June 2009, Pages 2819-2825
نویسندگان
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