کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186220 1381098 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Soluble polyphenylene homopolymers with controllable microstructure and properties: Optical and electrical characteristics of completely dehydrogenated poly(1,3-cyclohexadiene) as a π-conjugated polymer semiconductor
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Soluble polyphenylene homopolymers with controllable microstructure and properties: Optical and electrical characteristics of completely dehydrogenated poly(1,3-cyclohexadiene) as a π-conjugated polymer semiconductor
چکیده انگلیسی

The optical and electrical characteristics of soluble polyphenylene (PPH) homopolymers obtained by the complete dehydrogenation of poly(1,3-cyclohexadiene) (PCHD) are reported for the first time. The optical properties were strongly affected by the molar ratios of 1,2-/1,4-phenylene (Ph) units. The HOMO and LUMO energy levels were approximately −5.2 and −2.0 eV, and the microstructure did not influence those energy levels or the band gap energies. The generation of carriers (both electron and hole) in the polymer films was observed, and the drift mobility of electrons and holes was affected by the molar ratios of 1,2-/1,4-Ph units in the polymer chain. The drift mobility of electrons in PPH homopolymers with a high content of 1,4-Ph units was in the order of 10−4 to 10−5 (cm2/Vs). The I-V characteristics of soluble PPH homopolymers were controllable by the microstructure of PPH. The 1,2-Ph unit imparted appropriate solubility and toughness to the PPH homopolymers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 20, 20 September 2006, Pages 7123-7130
نویسندگان
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