کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186293 1381100 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dielectric properties of polymer nanoparticle composites
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Dielectric properties of polymer nanoparticle composites
چکیده انگلیسی

Well-dispersed high dielectric permittivity titanium dioxide (TiO2) nanoparticles were synthesized utilizing a block copolymer as a template. The nanoparticles were confined within microphase separated domains of sulfonated styrene-b-(ethylene-ran-butylene)-b-styrene (S-SEBS) block copolymers. A crosslinker (vinyltrimethoxysilane) was incorporated into the block copolymer matrices in order to decrease the dielectric loss from the free sulfonic acid groups. Dynamic mechanical analysis experiments confirmed that nanoparticles and crosslinker were confined within the crosslinked sulfonated styrene blocks and had no effect on the chain relaxation behavior of [ethylene-ran-butylene] blocks. Dielectric experiments showed that higher permittivity composites can thus be obtained with a significant decrease in loss tan δ (<0.01) when crosslinked with vinyltrimethoxysilane.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 48, Issue 3, 26 January 2007, Pages 791-798
نویسندگان
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