کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5186300 | 1381100 | 2007 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Largely improved toughness of PP/EPDM blends by adding nano-SiO2 particles Largely improved toughness of PP/EPDM blends by adding nano-SiO2 particles](/preview/png/5186300.png)
As a part of long-term project aimed at super polyolefin blends, in this work, we report the toughness and phase morphology of polypropylene (PP)/EPDM/SiO2 ternary composites. Two processing methods were employed to prepare PP/elastomer/filler ternary composites. One was called one-step processing method, in which the elastomer and the filler directly melt blended with PP matrix. Another one was called two-step processing method, in which the elastomer and the filler were mixed first, and then melt blended with pure PP. Two kinds of PP (grafted without or with maleic anhydride (PP-g-MA)) and SiO2 (treated with or without coupling agent) were used to control the interfacial interaction among the components. The dependence of the phase morphology on interfacial interaction and processing method was investigated. It was found that the formation of filler-network structure could be a key for a simultaneous enhancement of toughness and modulus of PP and its formation seemed to be dependent on the work of adhesion (WAB) and processing method. As the WAB of PP/EPDM interface was much lower than that of PP/SiO2 and EPDM/SiO2, and the two-step processing method was used, the formation of filler-network structure was favorable. In this case, a super toughened PP ternary composite with the Izod impact strength 2-3 times higher than PP/EPDM binary blend and 15-20 times higher than pure PP could be achieved.
Journal: Polymer - Volume 48, Issue 3, 26 January 2007, Pages 860-869