کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186667 1381110 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents
چکیده انگلیسی

This paper reports the synthesis of a novel maleimide-terminated thioetherimide oligomer and its copolymerization with reactive solvents bearing vinyl. Starting from 3-chlorophthalic anhydride and 4-chlorophthalic anhydride, 2,2′,3,3′-thiodiphenyl tertracaboxylic dianhydride (3,3′-TDPA) and 3,3′,4,4′-thiodiphenyl tertracaboxylic dianhydride (4,4′-TDPA) were synthesized. Thereby, a novel maleimide-terminated thioetherimide oligomer was prepared from. 3,3′-TDPA, 4,4′-TDPA, 3,3′-dimethyl-4,4′-diaminodiphenylmethane (DMMDA) and maleic anhydride. Binary and ternary copolymer resin were derived from corresponding binary and ternary homogeous solution consisting of thioetherimide oligomer, reactive solvent N-vinylpyrrolidone (NVP) or N,N′-dimethylacrylamide (DMAA) and divinylbenzene (DVB) as modifier, initiated either by gamma ray irradiation or by benzoyl peroxide (BPO). Thermal and mechanical properties of copolymer resin are determined and compared in terms of the kind of reactive solvent, addition of modifier DVB. The effect of initiation approach on property of final copolymer resin were studied. Phase separation and sub-transition of ternary copolymer resin induced by BPO are observed, which could be accounted for by thermal movement of DMAA molecules during thermal initiation. Structure-property relationship of copolymer resin was discussed. The effect of monomer molar ratio of 3,3′-TDPA and 4,4′-TDPA on thermal and mechanical properties were investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 3, 25 January 2006, Pages 937-945
نویسندگان
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