کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5186899 | 1381116 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chain contraction at the critical overlap concentration
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The sedimentation of dissolved macromolecules is analyzed in both the regions of very dilute solution and in semidilute regime employing the fractal aggregate model of macromolecular coils and blobs. The macromolecules entering the overlapping region are represented by more compact aggregates than that modeling the individual macromolecule of the same mass and fractal dimension. This regularity is confirmed by analyzing the hydrodynamic behavior of several polymer-solvent systems in a wide interval of fractal dimension including the polymers dissolved in both the theta and real solvents. The reduced hydrodynamic volume of macromolecules is about 0.3-0.5 of that of the individual macromolecule. This well corresponds with the literature data obtained by measurement of the reduction of the static correlation length with concentration and those determined by dielectric study of the end-to-end distance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 18, 23 August 2006, Pages 6257-6262
Journal: Polymer - Volume 47, Issue 18, 23 August 2006, Pages 6257-6262
نویسندگان
Lech Gmachowski,