کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5186904 1381116 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nanocomposites of isotactic polypropylene reinforced with rod-like cellulose whiskers
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Nanocomposites of isotactic polypropylene reinforced with rod-like cellulose whiskers
چکیده انگلیسی

Nanocomposite films of isotactic polypropylene reinforced with cellulose whiskers highly dispersed with surfactant were prepared for the first time and compared with either bare or grafted aggregated whiskers. Films obtained by solvent casting from toluene were investigated by means of X-ray diffraction, differential scanning calorimetry, dynamic mechanical analysis and tensile testing. Evaluation of the crystallization behavior showed that the aggregated or surfactant-modified whiskers induced two crystalline forms (α and β) in the nanocomposites and also acted as nucleating agents for isotactic polypropylene. The linear mechanical properties above the glass-rubber transition were found to be drastically enhanced for all three of the nanocomposites as compared to the neat polypropylene matrix, and these effects were attributed to a mechanical coupling between the polypropylene crystallites and filler/filler interactions. For the mechanical experiments at large deformations, the quality of the whisker dispersion was found to play a major role. The nanocomposites obtained with the surfactant-modified whiskers exhibited enhanced ultimate properties when compared to the neat matrix or to the composites containing the other filler types.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 18, 23 August 2006, Pages 6285-6292
نویسندگان
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