کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5186945 | 1381117 | 2010 | 5 صفحه PDF | دانلود رایگان |
Reversible addition-fragmentation chain transfer (RAFT) cryopolymerizations of acrylamides and acrylates were successfully carried out at â5 °C with cumene hydroperoxide/ascorbic acid as redox initiation couple and 2-dodecylsulfanyl- thiocarbonylsulfanyl-2-methylpropinoic acid as chain transfer agent. The cryopolymerization features of N,N-dimethylacrylamide (DMA) and tert-butyl acrylate (tBA) were investigated in view of kinetics, molecular weight and its distribution by proton nuclear magnetic resonance analysis and gel permeation chromatography. Furthermore, sequential block cryopolymerizations of N-isopropylacrylamide were performed with the obtained trithiocarbonate- functionalized PDMA or PtBA as macro-CTA and the corresponding block polymers were obtained. All the results demonstrated that these cryopolymerizations bear all the characteristics of controlled/living radical polymerizations.
Journal: Polymer - Volume 51, Issue 1, 6 January 2010, Pages 110-114