کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187000 | 1381118 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Architecture dependence of thermal fluctuation effects on the order-disorder transition of block copolymer melts
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Small-angle X-ray scattering has done to explore the difference in the strength of the thermal fluctuation effects between A-B diblock copolymer and (A/2)2-B Y-shaped copolymer. SAXS profiles for both systems in their disordered states were analyzed with the Brazovskii-type non-mean field theory by Fredrickson and Helfand. The analyses yielded Ginzburg number characterizing the strength of thermal fluctuation effects. Ginzburg number of Y-shaped copolymer is larger than that of diblock copolymer, suggesting that the strength of the thermal fluctuation effects is affected by the architecture of copolymers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 12, 10 June 2008, Pages 2979-2984
Journal: Polymer - Volume 49, Issue 12, 10 June 2008, Pages 2979-2984
نویسندگان
Ken-ichi Nakamura, Shotaro Nishitsuji, Mikihito Takenaka, Makoto Ouchi, Mitsuo Sawamoto,