کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187024 | 1381119 | 2005 | 8 صفحه PDF | دانلود رایگان |
Solution 17O NMR spectroscopy was used for structure elucidation of siloxane copolymers with the natural abundance of 17O, i.e. without any enrichment prior to spectroscopy. Homo, co, and terpolymers, as well as linear chains, cyclic oligomers, and graft polymers were investigated. All relevant chemical shifts and corresponding linewidths were reported for siloxane polymers substituted with methyl, phenyl, 3-cyanopropyl, 2-cyanoethyl, 3,3,3-trifluoropropyl, and polyethylene glycol ligands and with the backbone stiffening groups tetramethyl-p-silphenylene, tetramethyl-p,pâ²-sildiphenylene ether, and m-carborane. An increment system was extended to predict the chemical shifts of substituted siloxane copolymers. 17O NMR spectroscopy of polysiloxanes provided information concerning their chemical composition, average molecular weight, and microstructure.
Journal: Polymer - Volume 46, Issue 17, 8 August 2005, Pages 6447-6454