کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5187407 1381129 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
1,3-Dipolar cycloaddition polymerization reactions of novel macromolecules containing sym-tetrazine rings
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
1,3-Dipolar cycloaddition polymerization reactions of novel macromolecules containing sym-tetrazine rings
چکیده انگلیسی

We report the synthesis of sym-1,4-diphenyl-1,4-dihydro-1,2,4,5-polytetrazine through 1,3-dipolar cycloaddition polymerization reactions where bis-hydrazonoyl chloride was converted to a tetrazine based polymer through bis-nitrilimine intermediates. Polymer molecular weights approached 90,000 g/mol under optimized reaction conditions with low polydispersity indices of approximately 1.05. The polymers are soluble in a variety of organic solvents and the reactions were characterized through a series of spectral, thermal and chromatographic techniques. The tetrazine based polymers display high complexation potential with cobalt chloride demonstrating metal complexation capability.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 9, 29 April 2008, Pages 2253-2259
نویسندگان
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