کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187519 | 1381131 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polystyrenes with macro-intercalated organoclay. Part I. Compounding and characterization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Nanocomposites of polystyrene (PS) were prepared using a melt compounding or co-solvent method. Two commercial PS were used, and two organoclays-one prepared in this laboratory (COPS), and the other commercial Cloisite® 10A (C10A). The COPS is a product of clay intercalation with a copolymer of styrene and vinyl benzyl tri-methyl ammonium chloride. According to the XRD diffraction data, the clay platelets in COPS and its PNC with PS were relatively well dispersed, i.e. with the interlayer spacings of d001=7-8Â nm. By contrast, d001 in PNC prepared with C10A was only 4Â nm. However, the number of clay platelets per stack in PS/COPS was found to be significantly larger than that in PS/C10A, viz. m=3-12, compared to m=2-6. The scanning and transmission electron microscopy indicated that in the PS matrix COPS existed in form of large, immiscible domains.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 25, 28 November 2005, Pages 11557-11568
Journal: Polymer - Volume 46, Issue 25, 28 November 2005, Pages 11557-11568
نویسندگان
Maryam Sepehr, Leszek A. Utracki, Xiaoxia Zheng, Charles A. Wilkie,