کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5187652 | 1381134 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Poly(N-phenylmaleimides) bearing chiral oxazolinyl pendant: Supramolecular aggregation and enantioselectivity in fluorescence response
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
N-Phenylmaleimide derivatives bearing a chiral oxazoline substituent at the benzene ring (N-[o-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]maleimides, OPMIs) were polymerized using a binary initiating system composed of Et2Zn and n-BuLi to in situ produce the zinc complexes of optically active poly(OPMI)s. The significant changes in chiroptical and fluorescent properties were observed for these polymers upon complexation with metal ions due to the formation of supramolecular structure, evidenced by circular dichroism, fluorescence spectrum and atomic force microscopy. The fluorescence spectra of poly(OPMI)/ZnII complexes in the presence of (R)/(S)-1,1â²-bi-2-naphthol (BINOL) and (R)/(S)-2-amino-1-propanol were studied in THF media. It was found that the fluorescence intensity of the complexes responded differently to both enantiomers of BINOL and the amino alcohol in a quenching and enhancement fashion, respectively. Furthermore, the enantioselective fluorescence response was strongly dependent on the amount of incorporated zinc in polymer matrices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 49, Issue 8, 15 April 2008, Pages 2065-2070
Journal: Polymer - Volume 49, Issue 8, 15 April 2008, Pages 2065-2070
نویسندگان
Xiujuan Xi, Liping Lou, Liming Jiang, Weilin Sun, Zhiquan Shen,