کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5188254 | 1381150 | 2007 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and properties of poly(diphenylacetylenes) containing siloxy and halogen/methyl groups and their desilylated membranes Synthesis and properties of poly(diphenylacetylenes) containing siloxy and halogen/methyl groups and their desilylated membranes](/preview/png/5188254.png)
Diphenylacetylenes containing both siloxy groups and halogen or methyl substituents (p-tert-BuMe2SiOC6H4CCC6H3R2, R = m,p-Cl,Cl; m,m-Cl,Cl; m,p-Br,Br; m,m-Br,Br; m,p-Me,Me; m,m-Me,Me, 1a-f, respectively) were polymerized with TaCl5-n-Bu4Sn catalyst to give high molecular weight polymers (2a-f) in good yields. Free-standing membranes were fabricated by casting from toluene solution. Desilylation of these siloxy group-containing polymer membranes with trifluoroacetic acid (TFA) afforded poly(diphenylacetylene) membranes having hydroxy groups (3a-f). Polymers 2a-f were soluble in low polar solvents such as toluene and CHCl3, while 3a-f were insoluble in these solvents. According to thermogravimetric analysis (TGA), 2a-f and 3a-f exhibited high thermal stability (T0 â¼340 and â¼390 °C, respectively). The gas permeability of the halogen-containing polymer membranes was higher than that of methyl group-containing ones. The PCO2/PN2 permselectivity ratios of polymer membranes 3a-f were in the range of 14-49. The points of 3a-f in the PCO2 vs PCO2/PN2 plot were located obviously above Robeson's upper bound.
Journal: Polymer - Volume 48, Issue 1, 5 January 2007, Pages 43-49