کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5189128 | 1381178 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A bipyridine-containing water-soluble conjugated polymer: Highly efficient fluorescence chemosensor for convenient transition metal ion detection in aqueous solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel sulfonato-functionalized water-soluble conjugated polymer (WSCP), which containing 2â²2-bipyridine units as receptors for transition metal ions in the main chain was successfully synthesized by Sonogashira-coupling reaction for the first time. This polymer could easily dissolve in water (5Â mg/mL) and some polar organic solvents such as methanol. Its fluorescence in aqueous solution can be completely quenched upon addition of transition metal ions. The Ksv of different transition metal ions in aqueous solution were much higher than previous reports in organic solutions and showed highest selectivity to Ni2+. These results opened opportunities for developing novel chemosensors by introducing selective fluorescent chromophore into the water-soluble conjugated backbone.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 15, 12 July 2006, Pages 5228-5232
Journal: Polymer - Volume 47, Issue 15, 12 July 2006, Pages 5228-5232
نویسندگان
Yi Chen, Qu-Li Fan, Pei Wang, Bing Zhang, Yan-Qin Huang, Guang-Wei Zhang, Xiao-Mei Lu, Hardy Sze On Chan, Wei Huang,