کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5189621 | 1381189 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, structure, thermal and mechanical properties of nanocomposites based on linear polymers and layered silicates modified by polymeric quaternary ammonium salts (ionenes)
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Polymer-clay composites has been prepared by melt blending an organo-bentonite with linear polymers (polyamide, polysterene and polypropylene) in a disk-screw extruder. In first time organo-clay was prepared by surface treatment of Na-forms bentonite with polymeric quaternary ammonium salts (PQAS). XRD indicated that organo-bentonite layers were exfoliated and dispersed into polyamide and polystyrene. Addition of 2Â wt% organo-bentonites (optimal concentration) to polyamide increased tensile strength by 53% and Sharpy impact by 140%. With the incorporation of 2Â wt% organo-bentonites (optimal concentration) into polystyrene the tensile strength increased to 28% and the Sharpy impact increased to 25%. For polypropylyne-organo-bentonites composites we did not observe delamination of layered structure, and as result absence of reinforcements. TGA showed that the polyamide and polystyrene nanocomposites have higher decomposition temperature in comparison with the original polymers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 26, 12 December 2005, Pages 12226-12232
Journal: Polymer - Volume 46, Issue 26, 12 December 2005, Pages 12226-12232
نویسندگان
Michail V. Burmistr, Kostyantyn M. Sukhyy, Valery V. Shilov, Policarpos Pissis, Anna Spanoudaki, Irina V. Sukha, Vitalij I. Tomilo, Yuri P. Gomza,