کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5189690 | 1381190 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polymer CommunicationStudy on the formation of β-crystal during the crystallization process of polypropylene reactor granule
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A notable amount of PP β-crystal (30%, by X-ray diffraction pattern) has been found in the PP samples as polymerized at normal static isothermal crystallization conditions without using any extra nucleating agents. Existence of catalyst residues in the sample is decisive, which slows down the crystallization rate facilitating the formation of β-form spherulites. Comparatively, high molecular weight PP favors the formation of β-form spherulites, deducting from no β-crystal detected in the degraded samples. Finally, high isotacticity is also required for obtaining qualitative β-form spherulites, demonstrated by increased β-crystal content after removal of weak crystalline fraction of the sample.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 48, Issue 19, 10 September 2007, Pages 5480-5483
Journal: Polymer - Volume 48, Issue 19, 10 September 2007, Pages 5480-5483
نویسندگان
Yuping Yuan, Bin Chen, Xuequan Zhang,