کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5189709 | 1381190 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile preparation of pH-responsive gelatin-based core-shell polymeric nanoparticles at high concentrations via template polymerization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Adopting gelatin as template macromolecules and acrylic acid (AA) as monomers, core-shell polymeric nanoparticles at a concentration of 30Â mg/mL was successfully prepared via template polymerization, in which polymerization of the monomer and self-assembly between the polymer and the template take place simultaneously. The self-assembly was driven by specific interactions between gelatin and PAA produced in-situ, leading to nanoparticles with insoluble inter-polymer complexes of PAA and gelatin as the core and soluble gelatin as the shell. DLS and electrophoretic light scattering techniques were used to monitor the in-situ polymerization process, which indicated a size shrinkage and a surface charge decrease of the nanoparticles. The structure and morphology of the nanoparticles were characterized by FT-IR, TEM and SFM. The structure stability of the nanoparticles was improved by selectively crosslinking gelatin with glutaraldehyde. The nanoparticles also exhibit excellent pH-response: when pH changed from acid to base, the particles' volume expanded more than 80 times.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 48, Issue 19, 10 September 2007, Pages 5639-5645
Journal: Polymer - Volume 48, Issue 19, 10 September 2007, Pages 5639-5645
نویسندگان
Youwei Zhang, Zhouxi Wang, Yansong Wang, Jiongxin Zhao, Chengxun Wu,