کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5189950 | 1381194 | 2007 | 9 صفحه PDF | دانلود رایگان |
Solid-state processing for the preparation of poly(p-phenylenesulfide) (PPS)-based nano-composites having finely dispersed layered fillers was conducted. The mixture of PPS and organically modified layered filler (OMLF) (95:5 wt./wt.) was subjected to the processing using thermostatted hot-press at ambient temperature and 150 °C, below Tm of PPS (i.e., PPS is still at the solid-state), and applying pressures of 7, 14 and 33 MPa for 30 s. The mixture exhibited disorder and delaminated layer structure with the thickness of 40-80 nm into PPS matrix. On the contrary, nano-composite prepared by melt compounding at 300 °C for 3 min showed the large stacked silicate layers in the PPS matrix. The solid-state processing led to delamination of the silicate layers and attained the discrete dispersion.
Journal: Polymer - Volume 48, Issue 14, 29 June 2007, Pages 4143-4151