کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5190043 1381196 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Near-surface morphology effect on tack behavior of poly(styrene-b-butadiene-b-styrene) triblock copolymer/rosin films
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Near-surface morphology effect on tack behavior of poly(styrene-b-butadiene-b-styrene) triblock copolymer/rosin films
چکیده انگلیسی
The correlation between near-surface morphology and tack behavior of poly(styrene-b-butadiene-b-styrene) triblock copolymer (SBS)/rosin ester films was investigated using probe tack tests, transmission electron microscopy and small-angle X-ray scattering. The SBS/rosin films with rosin composition between 10 and 20 wt% rosin, prepared by slow evaporation of toluene during solvent casting, exhibited uniform near-surface morphology of lamellae oriented parallel to the surface. However, due to the limited solubility of rosin in the PS domains, the rosin started to phase-separate from the PS domains at 15 wt%, and formed fully separated micron-sized domains above 20 wt% rosin. The probe tack force of the SBS/rosin films increased steadily when the near-surface domain orientation changed from perpendicular cylinder to parallel lamellae on addition of rosin. Specifically, for a given lamellar morphology and surface orientation, macrophase separation of rosin plays a critical role in determining the tack properties of SBS/rosin films.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 11, 17 May 2006, Pages 3889-3895
نویسندگان
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