کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5190095 | 1381198 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal crosslinking of ethene copolymers containing 1,2-cyclopropane units
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The possibility to obtain crosslinked polyethene (XLPE) from new ethene copolymers containing cyclopropane rings (C3), synthesized by ethene/1,3-butadiene copolymerizations with a hindered metallocene catalyst, has been explored. In particular, the thermal crosslinking of these copolymers, for C3 molar content in the range 0.3-2.7%, has been studied for annealing temperatures up to 200 °C and compared with the thermal behavior of other ethene-butadiene copolymers. Only for the ethene-C3 copolymers, the annealing procedures in the temperature range 160-200 °C lead to high gel fractions. These crosslinking processes occur in reasonable times and leave nearly unaltered the polymer crystallinity. Moreover, annealing procedures up to 140 °C do not produce appreciable crosslinking. All these features suggest that these new copolymers could be suitable for possible industrial fabrication processes of XLPE.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 9, 15 April 2005, Pages 2847-2853
Journal: Polymer - Volume 46, Issue 9, 15 April 2005, Pages 2847-2853
نویسندگان
Gabriella Cavallo, Vincenzo Venditto, Liana Annunziata, Stefania Pragliola, Pasquale Longo, Gaetano Guerra,