کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5190122 1381198 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Shear-induced crystallization in isotactic polypropylene containing ultra-high molecular weight polyethylene oriented precursor domains
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Shear-induced crystallization in isotactic polypropylene containing ultra-high molecular weight polyethylene oriented precursor domains
چکیده انگلیسی
Melt blends of short ultra-high molecular weight polyethylene (UHMWPE) fibers and isotactic polypropylene (iPP) were subjected to shear at 145 °C, above the melting point of polyethylene (PE). Structural evolution and final morphology were examined by in situ synchrotron X-ray scattering/diffraction as well as ex situ microbeam X-ray diffraction and high resolution scanning electron microscopy, respectively. Results indicate that the presence of oriented UHMWPE molten domains significantly facilitated the crystallization of iPP and enhanced the initial 'shish-kebab' structure leading to the final cylindritic morphology. It is argued that shear flow aligns the fibrillar UHMWPE domains, where the interfacial frictions between PE and iPP effectively retards the relaxation of iPP chains, allowing the aligned iPP chains to create a shish-like structure. Nucleation on the iPP shish initiates the folded chain lamellae (kebabs), which grow perpendicularly to the iPP/PE interface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 9, 15 April 2005, Pages 3096-3104
نویسندگان
, , , , ,