کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5190132 1381198 2005 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Monte Carlo simulation of microemulsion polymerization
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Monte Carlo simulation of microemulsion polymerization
چکیده انگلیسی
Monte Carlo simulation of chemically reacting systems based on the master equation was used to describe the stochastic time evolution of the microemulsion polymerization system. A model was developed to demonstrate its applicability for hexyl methacrylate and styrene microemulsion polymerization. The properties of final latex, such as the particle size and molecular weight distributions were obtained simultaneously. The polymerization behavior and properties of final latexes were well reproduced. The model is valuable in confirming or elucidating the various mechanisms in the polymerization. The entry and desorption mechanism was well established to account for the polymerization kinetics. The general polymerization behavior of hydrophobic monomer in microemulsions was properly simulated by the model proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 9, 15 April 2005, Pages 3175-3184
نویسندگان
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