کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5190255 1381201 2006 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Large deformation rate-dependent stress-strain behavior of polyurea and polyurethanes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Large deformation rate-dependent stress-strain behavior of polyurea and polyurethanes
چکیده انگلیسی

The thermoplastic elastomer polyurethane and the elastomeric thermoset polyurea are finding new applications in increasing the survivability of structures under impact loading, including those encountered in blast and ballistic events. However, the mechanical behavior of polyurea and polyurethane materials under these high rate conditions is relatively unknown. Here, the rate-dependent stress-strain behavior of one polyurea and three representative polyurethane materials is studied by dynamic mechanical analysis, quasi-static compression testing and split Hopkinson pressure bar (SHPB) testing. The polyurethane chemistries were chosen to probe the influence of the hard segment content on the mechanical behavior, where the volume fraction and the amorphous vs. crystalline structure of the hard segment domains were varied. The large strain stress-strain behavior of polyurea and polyurethane shows strong hysteresis, cyclic softening, and strong rate-dependence. The polyurethane with a non-crystalline well-dispersed hard segment morphology did not exhibit cyclic softening. The materials are observed to transition from a rubbery-like behavior under low strain rate (∼10−3-100 s−1) loading conditions to either a leathery or glassy-like behavior under high strain rate (∼10−3 s−1) loading conditions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 47, Issue 1, 3 January 2006, Pages 319-329
نویسندگان
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