کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5190575 | 1381211 | 2005 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Shear-induced crystallization of isotactic polypropylene within the oriented scaffold of noncrystalline ultrahigh molecular weight polyethylene
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Shear-induced crystallization of isotactic polypropylene (iPP) within the oriented scaffolds of noncrystalline ultrahigh molecular weight polyethylene (UHMWPE) was investigated by means of in situ synchrotron small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD). The study was carried out using iPP/UHMWPE blends under isothermal crystallization at 145 °C (i.e., above the melting point of polyethylene) and step shear (shear rate=60 sâ1, duration=5 s) conditions. The oriented and isotropic iPP crystalline phases were extracted from the 2D WAXD pattern, and their kinetics data were evaluated with the Avrami equation. The dominant component in the oriented iPP phase was a kebab structure, whose nanostructure dimensions were determined by a novel SAXS analysis scheme. The minor non-crystalline but oriented UHMWPE component played a key role in the nucleation of iPP, which could be explained in terms of mutual diffusion at the interface, resulting in a significant increase in the relaxation time of iPP chains. As a result, after shear, the interfacial iPP chains could also retain their orientation and formed oriented nuclei to initiate the kebab growth.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 20, 23 September 2005, Pages 8859-8871
Journal: Polymer - Volume 46, Issue 20, 23 September 2005, Pages 8859-8871
نویسندگان
Carlos A. Avila-Orta, Christian Burger, Rajesh Somani, Ling Yang, Gad Marom, Francisco J. Medellin-Rodriguez, Benjamin S. Hsiao,