کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5190766 | 1381216 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Copolymerization of trimethylene carbonate and 2,2-dimethyltrimethylene carbonate by rare earth calixarene complexes
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Rare earth (Nd, Y, La) p-tert-butylcalix[n]arene (n=4, 6, and 8) complexes alone have been developed to catalyze random and block copolymerizations of trimethylene carbonate (TMC) and 2,2-dimethyltrimethylene carbonate (DTC). The random or block structure and thermal behavior of the copolymers have been characterized by SEC, NMR, DSC, XRD and PLM. Random copolymer with Mw of 14,100 and Mw/Mn of 1.36 was prepared by neodymium p-tert-butylcalix[6]arene complex under the conditions: [TMC+DTC]0/[Nd]=400, 80 °C, 8 h. The reactivity ratios of TMC and DTC are measured to be rTMC=4.68 and rDTC=0.163, respectively. Random copolymerization could be well designed by the feeding ratio to prepare copolymers with controlled Tm and Tg. Only 8% TMC units in the polymer chain destroyed the crystallization of PDTC showing no Tm of the copolymer in the DSC analysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 19, 8 September 2005, Pages 8379-8385
Journal: Polymer - Volume 46, Issue 19, 8 September 2005, Pages 8379-8385
نویسندگان
Weipu Zhu, Jun Ling, Hong Xu, Zhiquan Shen,