Multiblock copolymers synthesized in aqueous dispersions using multifunctional RAFT agents

Triblock copolymers were synthesized in aqueous dispersions in two polymerization steps using a low molar mass difunctional dithiocarbamate-based RAFT agent, and in merely one polymerization step using a macromolecular difunctional dithiocarbamate-based RAFT agent. Segmented block copolymers containing several alternating blocks of different polarities were synthesized in miniemulsion in merely two polymerization steps by applying multifunctional, dithiocarbamate-based RAFT agents. All polymerizations showed a linear increase of M¯n with monomer conversion. Evidence that this novel synthetic concept resulted in the formation of (multi)block copolymers was obtained by combining normal gel permeation chromatography with gradient polymer elution chromatography.