کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5190821 | 1381218 | 2006 | 9 صفحه PDF | دانلود رایگان |
As a continuation of previous work involving synthesis of an allyl-functionalized hyperbranched polyimide, AT-PAEKI, we have studied the use of this reactive polymer as a modifier of bisphenol-A based bismaleimide resin (BPA-BMI). This was pursued in anticipation of improvements in processability as well as physical properties including glass transition temperature, elastic modulus, and fracture toughness. Apparent miscibility, indicated by optical clarity with a single Tg, was observed for compositions containing up to 16Â wt% AT-PAEKI. Additionally, we observed complete suppression of monomer crystallization and a slight increase in the overall cure exotherm. By rheological characterization, blends containing 4Â wt% AT-PAEKI were found to feature a dramatic (65-fold) reduction in the viscosity minimum during heating. Dynamic mechanical analysis (DMA) showed that the addition of 2, 4, 8Â wt%. AT-PAEKI increases the cured modulus by approximately 10% from a base value of 3.4Â GPa, while adding 16Â wt% AT-PAEKI decreases the modulus slightly to 3.3Â GPa. DMA also revealed that the cured glass transition temperature increases monotonically with the addition of AT-PAEKI. Fracture toughness was gauged using the single edge notched beam methodology to yield the critical stress intensity factor, KIC. Our results showed a modest toughening effect (from 0.48 to 0.55Â MPa m1/2) upon the addition of AT-PAEKI. We conclude that AT-PAEKI may serve as an effective reactive processing aid with slight improvements in Tg, modulus, and fracture toughness.
Journal: Polymer - Volume 47, Issue 8, 5 April 2006, Pages 2813-2821