کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5191253 1381228 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of methylsisesquioxane filler on the properties of ionic liquid based polymer electrolyte
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Effect of methylsisesquioxane filler on the properties of ionic liquid based polymer electrolyte
چکیده انگلیسی

Composite electrolyte comprising methylsisesquioxane (MSQ) filler and 1-butyl-3-methyl-imidazolium-tetrafluoroborate (BMImBF4) ionic liquid (IL) in poly(2-hydroxyethyl methacrylate) (PHEMA) matrix had been prepared. The polymer matrix was formed by free radical polymerization of HEMA macromer, and MSQ was produced in situ from methyl-trimethoxysilane by the sol-gel method. Infrared spectroscopy and dynamic mechanical analysis were employed to give insight into the interactions among the methylsisesquioxane filler, BMImBF4 and the PHEMA polymer matrix. The PHEMA-IL-MSQ hybrids and the PHEMA-IL electrolyte without MSQ were investigated regarding their ionic conductivity and thermal and electrochemical properties. BMImBF4 increased the thermal stability of the polymer and provided the ion conductivity; MSQ filler as the additive increased the mechanical strength of the polymer and provided the ion conductive pathway. The electrolyte with MSQ at the 10 wt% showed the highest ionic conductivity of 5×10−4 S cm−1 which was five times higher than that of the electrolyte without MSQ, and the electrochemical window was up to 3.6 V.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 18, 23 August 2005, Pages 7578-7584
نویسندگان
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