کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5191322 | 1381230 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption of amphiphilic polysaccharides onto polystyrene latex particles
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Adsorption properties of hydrophobically modified carboxymethylpullulans (HMCMP) with different degree of modification of alkyl chains (C8) onto polystyrene latex particles have been investigated. Hydrophobic interactions between the grafted alkyl chains and the surface are responsible for the adsorption of these polymers. Their adsorption isotherms are Langmuir type, therefore, there is only a monolayer of adsorbed polymer chains. Variations of plateau adsorbed amounts and adsorbed layer thicknesses show a competition between the number of anchors (alkyl chains) and size of loops. Desorption of adsorbed polymer chains has been tested in three different media (0.1Â M NaCl, pure water and 0.01Â M NaOH). The greater desorbed amount has been obtained in 0.01Â M NaOH (hydrolysis of ester bonds).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 11, 11 May 2005, Pages 3700-3707
Journal: Polymer - Volume 46, Issue 11, 11 May 2005, Pages 3700-3707
نویسندگان
S. Simon, L. Picton, D. Le Cerf, G. Muller,