کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5191627 1381236 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Exceptional chiroptical behavior near ceiling temperature in free radical polymerization of menthyl 2-acetamidoacrylates
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Exceptional chiroptical behavior near ceiling temperature in free radical polymerization of menthyl 2-acetamidoacrylates
چکیده انگلیسی
Effect of polymerization conditions on chiroptical properties of polymer has been studied in the polymerization of (−)- and (+)-menthyl 2-acetamidoacrylates using radical initiators under the conditions with various temperatures, monomer concentrations, and reaction times. Specific rotation and circular dichroism of the resulting polymers indicated that a ceiling temperature (Tc) affected the chiroptical properties of the polymers and the polymerizations would give preferentially a helical polymer through a radical vinyl polymerization near Tc. In addition, the helical structure of the polymer was maintained intact even heating at 120 °C in anisole.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 13, 17 June 2005, Pages 4635-4639
نویسندگان
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